GA121025: Fmoc-Ser(GlcNAcβ(1-3)GalNAc)-OH (Peracetate)

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Description

GA121025: Fmoc-Ser(GlcNAcβ(1-3)GalNAc)-OH (Peracetate)C44H53N3O20 943. 9 An Fmoc protected L serine building block carrying a GlcNAc1 3GalNAc disaccharide, designed for solid phase peptide synthesis (SPPS) of glycopeptides. The N Fmoc group is removed under standard base conditions (piperidine) during chain elongation, while the free carboxylic acid is available for coupling to the growing resin bound peptide. The sugar hydroxyl groups are protected as acetate esters (peracetate), which keep the glycan

27 / An α-L-rhamnose ligand equipped with a terminal carboxylic acid through a short butyl spacer

Fmoc-L-Ser(Galβ(1-3)GalNAc)-OH (Peracetate)

69 / / 1-α-Hydroxy Vitamin D2-d6 / Doxercalciferol-d6

including the mannose receptor (CD206) and DC-SIGN

α-D-GalNAc-Et-Azide

an enzymatic substrate/acceptor

/ β-D-GalNAc-Pentyl-Amine (Boc protected

Galactobiose (Galβ(1-3)GalNAc) linked to biotin via a short triethylene glycol (PEG3) spacer

α-L-Rha-Et-SH

α-D-Man-Et-N3

31 / A β-D-glucose ligand equipped with a thioacetate-protected thiol linker through a short ethyl spacer

and mechanism of action studies